By David G. Gorenstein
ISBN-10: 0122917502
ISBN-13: 9780122917509
The choice first bargains details at the ideas and empirical observations of phosphorus-31 chemical shifts and the foundations and purposes of phosphorus-31 spin-spin coupling constants. Discussions specialise in advent and easy ideas, at once bonded phosphorus coupling constants, and two-bond and three-bond coupling constants. The textual content then ponders on phosphorus-31 NMR of enzyme complexes and paramagnetic probes of enzyme complexes with phosphorus-containing compounds.
The manuscript elaborates at the use of chiral thiophosphates and the stereochemistry of enzymatic phosphoryl move and DNA and RNA conformations. issues contain helix-coil transitions, series dependence of double-stranded DNA conformations, dynamic habit of RNA and DNA, organic and genetic value, and stereochemical difficulties studied with chiral thiophosphates. The conformation and dynamics of nucleic acids and phosphoproteins, leisure habit of nucleic acids, and concept and purposes of solid-state phosphorus-31 NMR to nucleic acids also are mentioned.
The choice is a necessary reference for readers attracted to the foundations and purposes of phosphorus-31 nuclear magnetic resonance.
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Phosphorous-31 NMR: Principles and Applications by David G. Gorenstein
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